PUBLICATIONS

24. Segizbayev, M.; Öztopçu, Ö.; Hayrapetyan, D.; Shakhman, D.; Lyssenko, K. A.; Khalimon, A. Y. "Transfer Hydrogenation of Aldehydes and Ketones Catalyzed using an Aminophosphinite POCNH Pincer Complex of Ni(II)." Dalton Trans. 2020, 49, 11950-11957. link

23. Hayrapetyan, D.; Khalimon, A. Y. "Catalytic Nitrile Hydroboration: A Route to N,N-Diborylamines and Uses Thereof." Chem. Asian J. 2020, 15, 2575-2587. link

22. Gudun, K. A.; Slamova, A; Hayrapetyan, D.; Khalimon, A. Y. "Efficient Co‐catalyzed Double Hydroboration of Nitriles: Application to One‐Pot Conversion of Nitriles to Aldimines." Chem. Eur. J. 2020, 26, 4963-4968. link

21. Khalimon, A. Y.; Gudun, K. A.; Hayrapetyan, D. "Base Metal Catalysts for Deoxygenative Reduction of Amides to Amines." Catalysts 2019, 9, 490 (contribution to the special issue "Coordination Chemistry and Catalysis"). link

20. Gudun, K. A.; Segizbayev, M.; Adamov, A.; Plessow, P. N.; Lyssenko, K. A.; Balanay, M. P.; Khalimon, A. Y. "POCN Ni(II) pincer complexes: synthesis, characterization and evaluation of catalytic hydrosilylation and hydroboration activities." Dalton Trans. 2019, 48, 1732‐1746. link

19. Nurseiit, A.; Janabel, J.; Gudun, K. A.; Kassymbek, A.; Segizbaev, M.; Seilkhanov, T. M.; Khalimon, A. Y. "Bench‐Stable Cobalt Pre‐Catalysts for Mild Hydrosilative Reduction of Tertiary Amides to Amines and Beyond." ChemCatChem 2019, 11, 790‐798. link 

18. Khalimon, A. Y.; Farha, P. M.; Nikonov, G. I. "Imido‐hydrido Complexes of Mo(IV): Catalysis and Mechanistic Aspects of Hydroboration Reactions." Dalton Trans. 2015, 44, 18945‐18956. link

17. Khalimon, A. Y.; Shaw, B. K.; Marwitz, A. J. V.; Piers, W. E.; Blackwell, J. M.; Parvez, M. "Photo Lewis acid generators: Photorelease of B(C6F5)3 and applications to catalysis." Dalton Trans. 2015, 44, 18196‐18206. link 

16. Huguet, N.; Jevtovikj, I.; Gordillo, A.; Lejkowski, M. L.; Lindner, R.; Bru, M.; Khalimon, A. Y.; Rominger, F.; Schunk, S. A.; Hofmann, P.; Limbach, M. "Catalytic and direct carboxylation of olefins with CO2: One‐pot synthesis of α,β‐unsaturated carboxylic acid salts." Chem. Eur. J. 2014, 20, 16858‐16862. link

15. Khalimon, A. Y.; McLeod, N. A.; Ignatov, S. K.; Okhapkin, A. I.; Kuzmina, L. G.; Nikonov, G. I. "Multiple coupling of silanes with an imido Mo complex." Dalton Trans. 2014, 43, 8446‐8453. link

14. Khalimon, A. Y.; Ignatov, S. K.; Simionescu, R.; Kuzmina, L. G.; Howard, J. A. K.; Nikonov,G. I. "Unusual Structure, Fluxionality, and Reaction Mechanism of Carbonyl Hydrosilylation by Silyl Hydride Complex [(ArN=)Mo(H)(SiH2Ph)(PMe3)3]." Chem. Eur. J. 2013, 19, 8573‐8590. link

13. Khalimon, A. Y.; Peterson, E.; Lorber, C.; Kuzmina, L. G.; Howard, J. A. K.; van der Est, A.; Nikonov, G. I. "Imido Supported Borohydrides of Titanium, Vanadium and Molybdenum." Eur. J. Inorg. Chem. 2013, 2205‐2211. link

12. Khalimon, A. Y.; Leitao, E. M.; Piers, W. E. "Photogeneration of a Phosphonium Alkylidene Olefin Metathesis Catalyst." Organometallics 2012, 31, 5634‐5637. link

11. Khalimon, A. Y.; Piers, W. E.; Blackwell, J. M.; Michalak, D. J.; Parvez, M. "A Photo Lewis Acid Generator (PhLAG): Controlled Photo Release of B(C6F5)3." J. Am. Chem. Soc. 2012, 134, 9601‐9604. link

10. Khalimon, A. Y.; Shirobokov, O. G.; Peterson, E.; Simionescu, R.; Kuzmina, L. G.; Howard, J. A. K.; Nikonov, G. I. "Mechanistic Aspects of Hydrolsilylation Catalyzed by(ArN=)Mo(H)(Cl)(PMe3)3." Inorg. Chem. 2012, 51, 4300‐4313. link

9. Khalimon, A. Y.; Ignatov, S. K.; Simionescu, R.; Kuzmina, L. G.; Howard, J. A. K.; Nikonov, G. I. "An unexpected mechanism of hydrosilylation by a silyl hydride complex of Mo." Inorg. Chem. 2012, 51, 754‐756. link

8. Khalimon, A. Y.; Farha, P.; Kuzmina, L. G.; Nikonov, G. I. "Catalytic Hydroboration Mediated by an Imido‐Hydrido Complex of Mo(IV)." Chem. Commun. 201248, 455‐457. link

7. Khalimon, A. Y.; Simionescu, R.; Nikonov, G. I. "Catalytic and Stoichiometric Reactivity of β-Silylamido Agostic Complex of Mo: Intermediacy of a Silanimine Complex and Applications to Multicomponent Coupling." J. Am. Chem. Soc. 2011, 133, 7033‐7053. link

6. Ignatov, S. K.; Khalimon, A. Y.; Rees, N. H.; Razuvaev, A. G.; Mountford, P.; Nikonov, G. I. "β-Agostic Silylamido and Silyl-Hydrido Compounds of Molybdenum and Tungsten." Inorg. Chem. 2009, 48, 9605‐9622 (Front Cover). link

5. Peterson, E.; Khalimon, A. Y.; Simionescu, R.; Kuzmina, L. G.; Howard, J. A. K.; Nikonov, G. I. "Diversity of Catalysis by an Imido‐Hydrido Complex of Molybdenum. Mechanism of Carbonyl Hydrosilylation and Silane Alcoholysis." J. Am. Chem. Soc. 2009, 131, 908‐909. link

4. Khalimon, A. Y.; Simionescu, R.; Kuzmina, L. G.; Howard, J. A. K.; Nikonov, G. I. "Agostic NSi‐HMo Complexes: From Curiosity to Catalysis." Angew. Chem., Int. Ed. 2008, 47, 7701‐7704. link. Angew. Chem. 2008, 120, 7815-7818. link

3. Khalimon, A. Y.; Holland, J. P.; Kowalczyk, R. M.; McInnes, E. J. L.; Green, J. C.; Mountford, P.; Nikonov, G. I. "Synthesis and molecular and electronic structure of an unusual paramagnetic borohydride complex Mo(NAr)2(PMe3)2(η2‐BH4)." Inorg. Chem. 2008, 47, 999‐1006. link

2. Khalimon, A. Y.; Lin, Z.; Simionescu, R.; Vyboishchikov, S. F.; Nikonov, G. I. "Persistent silylium ions stabilised by polyagostic Si-H∙∙∙Si interactions." Angew. Chem., Int. Ed. 2007, 46, 4530‐4533. link. Angew. Chem. 2007, 119, 4614-4617. link

1. Khalimon, A. Y.; Dorogov, K. Yu.; Churakov, A. V.; Kuzmina, L. G.; Lemenovskii, D. A.; Howard, J. A. K.; Nikonov, G. I. "Synthesis and structural studies of germyl and germyl/stannyl substituted tungstenocenes." Dalton Trans. 2007, 2440‐2449. link

PATENTS

Piers, W. E.; Khalimon, A. Y.; Marwitz, A. J. V. "Methods and Compounds for Photo Lewis Acid Generation and Uses Thereof." PCT Int. Appl. 2013, WO 2013/142956( A1). link

CONFERENCES AND INVITED TALKS

1. A. Y. Khalimon, K. Y. Dorogov, G. I. Nikonov, Synthesis of stannyl and germyl substituted tungstenocenes, Graduate students international conference in fundamental science “Lomonosov‐2003”, Moscow, Russia, April 15‐18, 2003, p. 89.

2. A. Y. Khalimon, K. Y. Dorogov, G. I. Nikonov, Synthesis of tungstenocens with stannyl and germyl ligands, “Modern Trends in Organometallic and Catalytic Chemistry”, Mark Vol'pin (1923‐1996) Memorial International Symposium, Russia, Moscow, May 18‐23, 2003, P47.

3. A. Y. Khalimon, K. Y. Dorogov, G. I. Nikonov, Synthesis of asymmetric stannyl and germyl substituted tungstenocenes, Graduate students international conference in fundamental science “Lomonosov‐2004”, Moscow, Russia, April 12‐15, 2004.

4. A. Y. Khalimon, K. Y. Dorogov, G. I. Nikonov, Synthesis of asymmetric tungstenocenes with stannyl and germyl ligands, “Modern Trends in Organoelement and Polymer Chemistry”, International Conference Dedicated to 50th Anniversary of A.N. Nesmeyanov Institute of Organoelement Compounds (INEOS), Russian Academy of Science, Russia, Moscow, May 30 – June 4, 2004, P78.

5. A.Y. Khalimon, K. Y. Dorogov, G. I. Nikonov, New synthetic approaches to germyl substituted tungstenocenes, 10th Russian National Conference “Organosilicon Compounds: Synthesis, Properties and Application”, Russia, Moscow, May 26‐30, 2005, 2C29.

6. A. Y. Khalimon, Z. Lin, R. Simionescu, G. I. Nikonov, Persistent silylium ions stabilized by polyagostic Si‐H…Si interactions, 40th Inorganic Discussion Weekend “IDW 2007”, University of Toronto, Toronto, ON, Canada, November 2‐4, 2007, T20.

7. E. Peterson, A. Y. Khalimon, G. I. Nikonov, Synthesis and catalytic reactivity of molybdenum imido hydrides, 40th Inorganic Discussion Weekend “IDW 2007”, Toronto, ON, Canada, November 2 ‐ 4, 2007, P66.

8. A. Y. Khalimon, Agostic NSi‐H‐M Complexes: From Curiosity to Catalysis, T. Hudlicky Seminar Series, Chemistry Department, Brock University, St. Catharines, ON, Canada, April 1, 2008. Invited Lecture.

9. E. Peterson, A. Y. Khalimon, G. I. Nikonov, Catalytic hydrosilation of carbonyls by molybdenum imido hydrides, 20th Canadian Symposium on Catalysis, Kingston, ON, Canada, June 15 ‐ 18, 2008, P124.

10. A. Y. Khalimon, G. I. Nikonov, Silylimido Agostic Complexes: From Curiosity to Catalysis, 41st Inorganic Discussion Weekend “IDW 2008”, Brock University, St. Catharines, ON, Canada, November 28‐30, 2008, T02.

11. A. Y. Khalimon, G. I. Nikonov, Unexpected Coupling Reactions of Unsaturated Organic Molecules with NSi‐H…Mo Agostic Complex, 92nd CSC, Hamilton, ON, Canada, May 30 – June 3, 2009, 443.

12. A. Y. Khalimon, G. I. Nikonov, Unexpected Catalytic and Stoichiometric Reactivity of Novel Mo(IV) Imido Silylhydrides, 93rd CSC, Metro Toronto Convention Centre, Toronto, ON, Canada, May 29 ‐ June 2, 2010, INP59.

13. A. Y. Khalimon, A. J. V. Marwitz, W. E. Piers, Controlled Photo Release of B(C6F5)3: A Photo Lewis Acid Generator, 95th CSC, Calgary, AB, Canada, May 26 – 30, 2012, 79.

14. A. Y. Khalimon, N. McLeod, G. I. Nikonov, S. K. Ignatov, A. J. Okhapkin, L. G. Kuzmina, Multicomponent Imido/Silane/Olefin Coupling on Mo Centres, 96th CSC, Quebec, Canada, May 26‐30, 2013, 868.

15. N. Huguet, I. Jevtovikj, C. Stieber, A. Khalimon, M. Bru, A. Gordillo, P. Ariyananda, P.‐N. Plessow, M. Limbach, Catalytic Formation of Sodium Acrylate from CO2 and Ethylene, 7th CaRLa Winter School 2014, Heidelberg, Germany, February 22‐28, 2014, P17.

16. P. N. Plessow, A. Y. Khalimon, S. C. E. Stieber, N. Huguet, I. Jevtovikj, R. Lindner, M. Lejkowski, A. Schäfer, M. Limbach, P. Hofmann, Acrylate Formation from CO2 and Ethylene Mediated by Nickel‐Complexes – Mechanistic Studies, 7th CaRLa Winter School 2014, Heidelberg, Germany, February 22‐28, 2014, P35.

17. M. Limbach, N. Huguet; I. Jevtovikj, C. S. Stieber, A. Khalimon, A. Gordillo, M. Bru, M. et al., CO2 as C1 building block for the synthesis of acrylates and beyond, 247th ACS National Meeting & Exposition, Dallas, TX, United States, March 16‐20, 2014, Abstracts of Papers, CATL‐116.

18. A. Y. Khalimon, From Fundamental Organometallic Chemistry to Applied Homogeneous Catalysis, SkolTech Seminar Series, Skolkovo Institute of Science and Technology, Skolkovo Innovation Center, Moscow, Russia, June 5, 2014. Invited lecture.

19. A. Nurseiit, M. Segizbayev, A. Y. Khalimon, Exploring Coordination Chemistry of 1,3‐substituted Azulenes, 100th Canadian Chemistry Conference and Exhibition, Toronto, ON, Canada, May 28 – June 1, 2017, 01478 INP.

20. K. Gudun, M. Segizbayev, A. Y. Khalimon, Phosphinite POCN Pincer Ligands: Synthesis and Coordination Chemistry, "Theoretical and Experimental Chemistry" VIth International Scientific Conference, dedicated to EXPO‐2017, Karaganda, Kazakhstan, 15‐17 June, 2017, Book of Abstracts, p. 21.

21. K. Gudun, M. Segizbayev, A. Adamov, A. Y. Khalimon, POCN pincer complexes of Ni(II): synthesis and hydrosilylation catalysis, Russian National Conference “Actual Problems of Organic Chemistry”, Novosibirsk – Sheregesh, Russia, March 12‐16, 2018.

22. A. Adamov, K. A. Gudun, M. Segizbayev, A. Y. Khalimon, Efficient, mild and chemoselective hydroboration of carbonyl compounds using posphinite POCN pincer
complexes of Nickel(II), "PBSi 2018" – International Conference on Phosphorus, Boron and Silicon, Barcelona, Spain, December 10‐12, 2018.

23. K. A. Gudun, M. Segizbayev, A. Y. Khalimon, Efficient Hydroboration of Carbonyl Compounds with Iminophosphinite POCN Pincer Complexes of Nickel, 257th ACS National Meeting, Orlando, Florida, USA, March 31 – April 04, 2019.

24. A. Y. Khalimon, K. A. Gudun, M. Segizbayev, A. Nurseiit, Nickel and cobalt pre‐catalysts for efficient reduction of carbonyl compounds and beyond, MC150 – Markovnikov Congress on Organic Chemistry devoted to the 150th anniversary of discovery of Markovnikov’s rule, Moscow – Kazan, Russia, 21‐28 June, 2019, O16.

Disclaimer - the views expressed here are those of the authors and not of Nazarbayev University

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